Bis(N-isopropyl-N-methyldithiocarbamato-κ2S,S′)(1,10-phenanthroline-κ2N,N′)zinc
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چکیده
منابع مشابه
Bis(N-isopropyl-N-methyldithiocarbamato-κ2 S,S′)(1,10-phenanthroline-κ2 N,N′)zinc
The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H⋯S, C-H⋯π(ZnS(2)C) and π-π [ring centroid distance between centrosymmetri...
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The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti-prism. A number of π-π stacking inter-actions involving the phen rings help to consolidate the crystal packing (centroid-centroid dista...
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In the title compound, C(11)H(14)ClNO, the herbicide propachlor, there are significant differences between the three N-C bond lengths [N-C(carbon-yl) = 1.354 (3) Å, N-C(phen-yl) = 1.444 (2) Å and N-C(isoprop-yl) = 1.496 (3) Å], indicating the presence of π delocalization involving the carbonyl group. The N atom lies 0.074 (2) Å from the plane defined by the the three bonded C atoms.
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Poly(N-isopropyl acrylamide) (pNIPAM) is one of the most popular stimulus-responsive polymers for research. It is especially of great interest in the field of tissue engineering. While it is known that the NIPAM monomer is toxic, there is little conclusive research on the cytotoxicity of the polymer. In this work, the relative biocompatibility of the NIPAM monomer, pNIPAM, and pNIPAM-coated sub...
متن کاملChloridobis(1,10-phenanthroline-κ2 N,N′)copper(II) tetrakis(nitrato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)terbate(III)
The title complex salt, [CuCl(C(12)H(8)N(2))(2)][Tb(NO(3))(4)(C(12)H(8)N(2))], consists of discrete [CuCl(phen))(2)](+) cations and [Tb(NO(3))(4)(phen)](-) anions (phen is 1,10-phenanthroline). The [CuCl(phen))(2)](+) cation contains a five-coordinate Cu(2+) ion, ligated by two bidentate phen ligands and one Cl(-) ion, exhibiting a distorted CuN(4)Cl trigonal-bipyramidal geometry. In the [Tb(NO...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811012499